Table of Contents
- 1 Are first order reactions linear?
- 2 Which order reaction is linear?
- 3 Is first order decay linear?
- 4 Why is the half-life of a first order reaction independent of concentration?
- 5 Why are initial rates of reaction used?
- 6 What is first order reaction determine the integrated rate equation for first order reaction?
Are first order reactions linear?
A first-order reaction is a reaction that proceeds at a rate that depends linearly on only one reactant concentration.
Which order reaction is linear?
A linear change in concentration with time is a clear indication of a zeroth-order reaction.
Why is rate of reaction linear?
The overall order of a reaction is determined by adding up the exponents. I.e. If a=1 and b=2, the reaction is third order overall. Reactions in which the rate varies with concentration of a single species, and the change in concentration is exponential, so that a plot of ln(concentration) v. time is linear.
Is first order decay linear?
28.3: First-Order Reactions Show an Exponential Decay of Reactant Concentration with Time. This form implies that a plot of the natural logarithm of the concentration is a linear function of the time.
Why is the half-life of a first order reaction independent of concentration?
If two reactions have the same order, the faster reaction will have a shorter half-life, and the slower reaction will have a longer half-life. Thus, for a first-order reaction, each successive half-life is the same length of time, as shown in Figure 1, and is independent of [A].
Why is the order of a reaction important?
The order of a reaction tells us how the rate of reaction is affected by the concentration of the reactants. For a zero-order reaction, the rate of reaction is independent of the concentration of reactants, so changing the reactant concentration will have no effect on the reaction rate.
Why are initial rates of reaction used?
The method of initial rates allows the values of these reaction orders to be found by running the reaction multiple times under controlled conditions and measuring the rate of the reaction in each case. All variables are held constant from one run to the next, except for the concentration of one reactant.
What is first order reaction determine the integrated rate equation for first order reaction?
For first-order reactions, the equation ln[A] = -kt + ln[A]0 is similar to that of a straight line (y = mx + c) with slope -k. This line can be graphically plotted as follows.
What does first order reaction mean?
Definition of first-order reaction : a chemical reaction in which the rate of reaction is directly proportional to the concentration of the reacting substance — compare order of a reaction.