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How do you predict coordination number of complexes?

Posted on September 28, 2022 by Author

How do you predict coordination number of complexes?

Here are the steps for identifying the coordination number of a coordination compound.

  1. Identify the central atom in the chemical formula.
  2. Locate the atom, molecule, or ion nearest the central metal atom.
  3. Add the number of atoms of the nearest atom/molecule/ions.
  4. Find the total number of nearest atoms.

What three factors determine the coordination number of a complex?

The most important factors that govern the CN of a complex are 1) The size of the central metal atom or ion. 2) The steric interaction between ligands. 3) Electronic interactions between the central atom or ion and the ligands.

What is coordination number give two examples of complexes having coordination number of 2 and 4?

Some examples include: [Ag(NH3)2]+ where Ag has coordination number 2 and the molecular geometry of the compound is linear. [NiCl4]2− where Ni has coordination number 4 and the molecular geometry of the compound is square planar.

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What is the coordination number of the complex ion Cu nh3 62 +?

6
Ans. The coordination number is 6. There are three bidentate ligands attached to the central metal, 3 x 2 = 6. 13.

What is the coordination number of the chromium ion in the complex ion CR en ₃ ³ ⁺?

For example, the coordination number of chromium(III) and cobalt(III) is invariably 6, and that of platinum(II) is always 4. However, the coordination numbers of most metal ions vary with the ligand. The most common coordination numbers are 4 and 6.

How does the coordination number depend on the structure of the metal?

Coordination numbers are normally between two and nine. The number of bonds depends on the size, charge, and electron configuration of the metal ion and the ligands. The s, p, and d orbitals of the metal can accommodate 18 electrons.

What are the factors affecting coordination number?

In simple terms, the coordination number of a complex is influenced by the relative sizes of the metal ion and the ligands and by electronic factors, such as charge which is dependent on the electronic configuration of the metal ion.

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What is coordination number in coordination compounds?

coordination number, also called Ligancy, the number of atoms, ions, or molecules that a central atom or ion holds as its nearest neighbours in a complex or coordination compound or in a crystal.

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